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- W2482160686 abstract "A critical survey of the literature on free radical polymerizations in the presence of phase transfer agents indicates that the majority of these reactions are initiated by transfer of an active species (monomer or initiator) from one phase to another, although the exact details of this phase transfer may be influenced by the nature of the phase transfer catalyst and reaction medium. Initial kinetic studies of the solution polymerization of methyl methacrylate utilizing solid potassium persulfate and Aliquat 336 yield the experimental rate law: Rp = k[MMA]1.6[Aliquat 336]0.2[K2S2O8]0.6 This expression is consistent with theory in the limiting case where the equilibrium constant for anion exchange at the interface is large." @default.
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- W2482160686 date "1987-12-19" @default.
- W2482160686 modified "2023-10-13" @default.
- W2482160686 title "Mechanistic Aspects of Phase-Transfer Free Radical Polymerizations" @default.
- W2482160686 doi "https://doi.org/10.1021/bk-1987-0326.ch010" @default.
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