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- W2482304891 abstract "Silicon-29 NMR provides a direct measurement of the average Al neighbor distribution in zeolite frameworks, from which the nature of the Si,Al ordering can be inferred. Comparison of 29Si NMR data for synthetic faujasites and A-type (ZK4) zeolites shows that the Si,Al distribution is different for these frameworks despite their having a common structural element, the sodalite cage. It is shown that the Si,Al distribution in faujasite crystals can be understood in terms of an ordered sub-unit, the single 6-ring, combined randomly within the framework topology in accordance with Loewenstein's rule as the only constraint. It is hypothesized that the difference between faujasite and ZK4 ordering lies in nature of the fundamental sub-unit." @default.
- W2482304891 created "2016-08-23" @default.
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- W2482304891 date "1983-05-17" @default.
- W2482304891 modified "2023-09-26" @default.
- W2482304891 title "Silicon and Aluminum Ordering of Zeolites: Interpretation of Silicon-29 NMR Data for Faujasite and ZK4" @default.
- W2482304891 doi "https://doi.org/10.1021/bk-1983-0218.ch015" @default.
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