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- W2482525286 abstract "The ionic defects characteristic of the fluorite lattice are interstitial anions and anion vacancies, and the actinide dioxides provide examples. Thermodynamic data for the uranium oxides show wide ranges of nonstoichiometry at high temperatures and the formation of ordered compounds at low temperatures. Analogous ordered structures are found in the Pa-O system, but not in the Np-O or Pu-O systems. Nonstoichiometric compounds exist between PuO2 and PuO1.6 at high temperatures, but no intermediate compounds exist at room temperature. The interaction of defects with each other and with metallic ions in the lattice is discussed." @default.
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- W2482525286 date "1963-01-01" @default.
- W2482525286 modified "2023-09-23" @default.
- W2482525286 title "Nonstoichiometry in Fluorite-Type Oxides" @default.
- W2482525286 doi "https://doi.org/10.1021/ba-1964-0039.ch006" @default.
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