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- W2482610312 abstract "The facile access to 3-bromo-2-pyrone allows the preparation of 6-bromo-2-trimethylsilyl-phosphinine by a [4+2] cycloaddition with Me3Si-C≡P for the first time. The regioselectivity of this reaction could be verified by means of single crystal X-ray diffraction of the corresponding W0 complex. In the presence of ZnBr2 and dppp (1,3-bis(diphenylphosphino)propane) as a bidentate ligand, the bromo-phosphinine quantitatively undergoes a Negishi cross-coupling reaction with PhLi that selectively leads to 6-phenyl-2-trimethylsilyl-phosphinine. This heterocycle could again be characterized by means of X-ray diffraction as a W0 complex. These results describe a new and convenient route to 2,6-disubstituted phosphinines that makes use of readily available starting materials." @default.
- W2482610312 created "2016-08-23" @default.
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- W2482610312 date "2016-08-02" @default.
- W2482610312 modified "2023-09-25" @default.
- W2482610312 title "3-Bromo-2-Pyrone: An Alternative and Convenient Route to Functionalized Phosphinines" @default.
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- W2482610312 doi "https://doi.org/10.1002/chem.201602012" @default.
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