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- W2482962019 abstract "For some years we have been studying di- and tri-metal complexes in which organic ligands bridge the metal centres. These ligands often display unusual chemical behaviour not found, or rarely found, in mononuclear metal compounds. For example in [Ru3(CO)8(C8H6)] the triruthenium cluster stabilises pentalene(1), an organic molecule having only a transient existence under normal conditions, while in the complex [Ni3(CO)3{µ3-(η2-CF3C2CF3)}{µ3-(η8-C8H8)}] the trinickel system bonds a planar cyclo-octatetraene ring(2). There are several known examples of situations where a ligand bridging a metal — metal bond displays unusual reactivity. Thus we have shown that alkynedimolybdenum complexes [Mo2(µ-RC2R) (CO) 4 (η-C5H5)2] undergo stepwise insertion reactions with alkyne molecules in a process which appears to depend on the dimolybdenum group alternating between Mo — Mo, Mo= Mo and Mo ≡ Mo bonding modes(3). Moreover, the acetylene molecule in the complex [Mo2(µ-HC2H) (CO) 4 (η-C5H5)2] shows Diels-Alder reactivity(4), unusual behaviour for this alkyne. In spite of the evident" @default.
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- W2482962019 date "1981-06-11" @default.
- W2482962019 modified "2023-10-16" @default.
- W2482962019 title "New Approaches to the Chemistry of Di- and Trimetal Complexes" @default.
- W2482962019 doi "https://doi.org/10.1021/bk-1981-0155.ch015" @default.
- W2482962019 hasPublicationYear "1981" @default.
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