Matches in SemOpenAlex for { <https://semopenalex.org/work/W2483013585> ?p ?o ?g. }
- W2483013585 endingPage "72" @default.
- W2483013585 startingPage "1" @default.
- W2483013585 abstract "This chapter focuses on the process of cryosynthesis of metal complexes. The use of metal vapors in organic and inorganic chemistry has led to the creation of a new area of synthetic coordination chemistry: the “direct synthesis” of metal complexes starting from metal vapors in the gas phase. Coordination compounds can be obtained in the gas phase by direct interaction of vaporized atomic metals and ligands. However, the scope of this approach is strongly limited by the instability of complexes at high temperatures. The highest efficiency in gas-phase syntheses is attained by co-condensation of metal vapors and ligands at low temperature. The types of apparatus used for direct synthesis of metal complexes in the gas phase differ according to the methods of metal evaporation used and of the introduction of the ligand into the reaction chamber. Various organic and inorganic ligands are used in cryosynthesis with the participation of atomic metals at low temperatures, and pure gas-phase reactions without a condensed phase at high temperatures hold many possibilities for the synthesis of various types of complex, especially π-complexes of aromatic and cyclodiene ligands. The chapter discusses the processes of synthesis of metal complexes with simple inorganic ligands, cryosynthesis of metal π- and σ-complexes, and vapor synthesis of metal chelates, highlighting the advantages and disadvantages of cryosynthesis." @default.
- W2483013585 created "2016-08-23" @default.
- W2483013585 creator A5016774184 @default.
- W2483013585 creator A5025622187 @default.
- W2483013585 date "1999-01-01" @default.
- W2483013585 modified "2023-09-25" @default.
- W2483013585 title "Cryosynthesis of Metal Complexes" @default.
- W2483013585 cites W116219015 @default.
- W2483013585 cites W1499260167 @default.
- W2483013585 cites W1526397678 @default.
- W2483013585 cites W1554710683 @default.
- W2483013585 cites W1572197469 @default.
- W2483013585 cites W1600443616 @default.
- W2483013585 cites W1887838720 @default.
- W2483013585 cites W1963686666 @default.
- W2483013585 cites W1964141150 @default.
- W2483013585 cites W1964521764 @default.
- W2483013585 cites W1965579338 @default.
- W2483013585 cites W1965986402 @default.
- W2483013585 cites W1966626313 @default.
- W2483013585 cites W1967040781 @default.
- W2483013585 cites W1967109262 @default.
- W2483013585 cites W1968296000 @default.
- W2483013585 cites W1969268098 @default.
- W2483013585 cites W1970440518 @default.
- W2483013585 cites W1970581129 @default.
- W2483013585 cites W1973226561 @default.
- W2483013585 cites W1974256374 @default.
- W2483013585 cites W1975603179 @default.
- W2483013585 cites W1975667462 @default.
- W2483013585 cites W1976754585 @default.
- W2483013585 cites W1977928443 @default.
- W2483013585 cites W1978679634 @default.
- W2483013585 cites W1979439506 @default.
- W2483013585 cites W1979545840 @default.
- W2483013585 cites W1979700185 @default.
- W2483013585 cites W1982184558 @default.
- W2483013585 cites W1983053105 @default.
- W2483013585 cites W1984371114 @default.
- W2483013585 cites W1984650599 @default.
- W2483013585 cites W1986309976 @default.
- W2483013585 cites W1987023196 @default.
- W2483013585 cites W1990422767 @default.
- W2483013585 cites W1990722175 @default.
- W2483013585 cites W1991464692 @default.
- W2483013585 cites W1992759765 @default.
- W2483013585 cites W1992882363 @default.
- W2483013585 cites W1993753511 @default.
- W2483013585 cites W1994935625 @default.
- W2483013585 cites W1995197075 @default.
- W2483013585 cites W1995501234 @default.
- W2483013585 cites W1996317064 @default.
- W2483013585 cites W1998292527 @default.
- W2483013585 cites W1998886927 @default.
- W2483013585 cites W2000424686 @default.
- W2483013585 cites W2000950727 @default.
- W2483013585 cites W2002169492 @default.
- W2483013585 cites W2007163158 @default.
- W2483013585 cites W2007203105 @default.
- W2483013585 cites W2007979768 @default.
- W2483013585 cites W2008648928 @default.
- W2483013585 cites W2008685887 @default.
- W2483013585 cites W2008903065 @default.
- W2483013585 cites W2010722984 @default.
- W2483013585 cites W2011368184 @default.
- W2483013585 cites W2011515615 @default.
- W2483013585 cites W2012689490 @default.
- W2483013585 cites W2015150474 @default.
- W2483013585 cites W2016534640 @default.
- W2483013585 cites W2020776565 @default.
- W2483013585 cites W2023539635 @default.
- W2483013585 cites W2023590112 @default.
- W2483013585 cites W2027020916 @default.
- W2483013585 cites W2028264133 @default.
- W2483013585 cites W2028954633 @default.
- W2483013585 cites W2030091916 @default.
- W2483013585 cites W2030760979 @default.
- W2483013585 cites W2031510238 @default.
- W2483013585 cites W2034142756 @default.
- W2483013585 cites W2034745057 @default.
- W2483013585 cites W2037098511 @default.
- W2483013585 cites W2037627884 @default.
- W2483013585 cites W2038407138 @default.
- W2483013585 cites W2038489836 @default.
- W2483013585 cites W2039986309 @default.
- W2483013585 cites W2041845759 @default.
- W2483013585 cites W2048966760 @default.
- W2483013585 cites W2049730927 @default.
- W2483013585 cites W2049974444 @default.
- W2483013585 cites W2050623451 @default.
- W2483013585 cites W2052343452 @default.
- W2483013585 cites W2052920613 @default.
- W2483013585 cites W2053104287 @default.
- W2483013585 cites W2053182936 @default.
- W2483013585 cites W2053411100 @default.
- W2483013585 cites W2054880490 @default.
- W2483013585 cites W2056990871 @default.
- W2483013585 cites W2058468913 @default.