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- W2483163313 abstract "Treatment of diazoalkane complexes [Ru(η5-C5Me5)(N2CAr1Ar2){P(OR)3}L]BPh4 (1–5) [Ar1Ar2Ph, Ar1Ph, Ar2p-tolyl, Ar1Ar2C12H8; RMe, Et; LP(OR)3, PPh3] with ethylene and maleic anhydride (ma) afforded η2-alkene derivatives [Ru(η5-C5Me5)(η2-CH2CH2){P(OR)3}(PPh3)]BPh4 (7, 8) and [Ru(η5-C5Me5)(η2-ma){P(OR)3}L]BPh4 (6, 9), respectively. Acrylonitrile also reacted with diazoalkane complexes 1–5 to give dipolar (3 + 2) cycloaddition, affording 3H-pyrazole derivatives [Ru(η5-C5Me5){P(OR)3}(PPh3)]BPh4 [A] and [Ru(η5-C5Me5){P(OR)3}(PPh3)]BPh4 [B] (10, 11). Treatment of complexes 1–5 with acetylene HCCH under mild conditions (1 atm, room temperature) led to dipolar cycloaddition, affording 3H-pyrazole complexes [Ru(η5-C5Me5){η1-}{P(OR)3}L]BPh4 (12, 15), whereas reaction with terminal alkynes HC≡CR gave vinylidene derivatives [Ru(η5-C5Me5){CC(H)R}{P(OR)3}L]BPh4 (13, 14, 16, 17). The complexes were characterised spectroscopically (IR and 1H, 31P, 13C NMR) and by X-ray crystal structure determination of [Ru(η5-C5Me5){P(OEt)3}2]BPh4 (12). A DFT study on the reaction of diazoalkane complexes with CH2CH2 is also reported." @default.
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- W2483163313 date "2016-11-01" @default.
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- W2483163313 title "Reactivity with alkene and alkyne of pentamethylcyclopentadienyl half-sandwich diazoalkane complexes of ruthenium" @default.
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- W2483163313 doi "https://doi.org/10.1016/j.jorganchem.2016.07.016" @default.
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