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• W2483456075 abstract "A new HPAs H20[P8W60Ta12(H2O)4(OH)8O236]·125H2O (H-1) which comprises a Ta/W mixed addenda heteropolyanion, 20 protons, and 125 crystalline water molecules has been prepared through ion-exchange method. The structure and properties of H-1 have been explored in detail. AC impedance measurements indicate that H-1 is a good solid state proton conducting material at room temperature with a conductivity value of 7.2×10−3 S cm−1 (25 °C, 30% RH). Cyclic voltammograms of H-1 indicate the electrocatalytic activity towards the reduction of nitrite. Hammett acidity constant H0 of H-1 in CH3CN is −2.91, which is the strongest among the present known HPAs. Relatively, H-1 exhibits excellent catalytic activities toward acetal reaction." @default.
• W2483456075 created "2016-08-23" @default.
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• W2483456075 date "2016-11-01" @default.
• W2483456075 modified "2023-10-16" @default.
• W2483456075 title "A Ta/W mixed addenda heteropolyacid with excellent acid catalytic activity and proton-conducting property" @default.
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• W2483456075 doi "https://doi.org/10.1016/j.jssc.2016.08.003" @default.
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