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- W2484073313 abstract "The effect of specific surface area and aspect ratio of different layered double hydroxides (LDHs) on flame retardant properties of PS/LDH nano-composites was systematically investigated. Carbonate LDH, with a Mg:Al molar ratio of 2:1, was synthesized by the urea hydrolysis method and external basal surfaces were selectively modified using a siderophilic ligand (3,4-dihydroxybenzo-phenone). The efficiency of this surface modification was investigated by studying the sedimentation kinetics in an organic solvent. PS/LDH nanocomposites were prepared by solution blending in a three roll mill. Cone calorimeter measurements showed little influence of specific surface areas but a pronounced influence of aspect ratio on flame retardancy. Optimizing aspect ratio yielded a significant reduction of the peak of heat release rate (PHRR) of 34 % at 5 wt% loading of LDH. A maximum reduction of PHRR of 51% could be achieved at a loading of 15wt%. Interestingly, at this loading an unusual increase of tign could be observed." @default.
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- W2484073313 date "2012-01-01" @default.
- W2484073313 modified "2023-09-27" @default.
- W2484073313 title "Significance of Aspect Ratio on Efficiency of Layered Double Hydroxide Flame Retardants" @default.
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- W2484073313 doi "https://doi.org/10.1021/bk-2012-1118.ch026" @default.
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