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- W2485013351 abstract "Oxidative dearomatization of 2- and 4-substituted phenols to their corresponding benzoquinone monoketals by catalytic amount of iodobenzene, and m-CPBA as a co-oxidant has been achieved via in situ generation of PhIO2, a hypervalent iodine(V) species. The transiently generated orthobenzoquinone monoketals further underwent Diels–Alder reaction with various dienophiles to furnish densely substituted bicyclo[2.2.2]octenones in high selectivities and yields. This methodology features ready availability of reagents, cost effectiveness, safety, brevity, selectivity, diversity and excellent yields." @default.
- W2485013351 created "2016-08-23" @default.
- W2485013351 creator A5047184505 @default.
- W2485013351 creator A5064822760 @default.
- W2485013351 date "2016-08-01" @default.
- W2485013351 modified "2023-09-27" @default.
- W2485013351 title "Iodobenzene and m-chloroperbenzoic acid mediated oxidative dearomatization of phenols" @default.
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- W2485013351 doi "https://doi.org/10.1016/j.tetlet.2016.07.078" @default.
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