FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2485081618> ?p ?o ?g. }

• W2485081618 endingPage "9" @default.
• W2485081618 startingPage "1" @default.
• W2485081618 abstract "The oxidation kinetics of fluorenone hydrazone (FH) using potassium permanganate in alkaline medium were measured at a constant ionic strength of 0.1 mol dm −3 and at 25°C using UV/VIS spectrophotometer. A first-order kinetics has been monitored in the reaction of FH with respect to [permanganate]. Less-than-unit order dependence of the reaction on [FH] and [OH − ] was revealed. No pronounced effect on the reaction rate by increasing ionic strength was recorded. Intervention of free radicals was observed in the reaction. The reaction mechanism describing the kinetic results was illustrated which involves formation of 1 : 1 intermediate complex between fluorenone hydrazones and the active species of permanganate. 9H-Fluorenone as the corresponding ketone was found to be the final oxidation product of fluorenone hydrazone as confirmed by GC/MS analysis and FT-IR spectroscopy. The expression rate law for the oxidation reaction was deduced. The reaction constants and mechanism have been evaluated. The activation parameters associated with the rate-limiting step of the reaction, along with the thermodynamic quantities of the equilibrium constants, have been calculated and discussed." @default.
• W2485081618 created "2016-08-23" @default.
• W2485081618 creator A5001512863 @default.
• W2485081618 creator A5037010369 @default.
• W2485081618 creator A5043179374 @default.
• W2485081618 creator A5047258036 @default.
• W2485081618 creator A5059444685 @default.
• W2485081618 date "2016-07-25" @default.
• W2485081618 modified "2023-09-26" @default.
• W2485081618 title "Kinetics and Mechanistic Study of Permanganate Oxidation of Fluorenone Hydrazone in Alkaline Medium" @default.
• W2485081618 cites W1958365682 @default.
• W2485081618 cites W1970543953 @default.
• W2485081618 cites W1987987542 @default.
• W2485081618 cites W1993212989 @default.
• W2485081618 cites W1998598460 @default.
• W2485081618 cites W2003925949 @default.
• W2485081618 cites W2004297608 @default.
• W2485081618 cites W2006475336 @default.
• W2485081618 cites W2013930267 @default.
• W2485081618 cites W2032486415 @default.
• W2485081618 cites W2048405337 @default.
• W2485081618 cites W2055499045 @default.
• W2485081618 cites W2056440558 @default.
• W2485081618 cites W2061554029 @default.
• W2485081618 cites W2063256624 @default.
• W2485081618 cites W2065778741 @default.
• W2485081618 cites W2076378769 @default.
• W2485081618 cites W2076787796 @default.
• W2485081618 cites W2086485118 @default.
• W2485081618 cites W2087749196 @default.
• W2485081618 cites W2091167066 @default.
• W2485081618 cites W2093809193 @default.
• W2485081618 cites W2099740152 @default.
• W2485081618 cites W2153236453 @default.
• W2485081618 cites W2156214323 @default.
• W2485081618 cites W2180524225 @default.
• W2485081618 cites W2313417627 @default.
• W2485081618 cites W2315026810 @default.
• W2485081618 cites W2461417312 @default.
• W2485081618 cites W2469728664 @default.
• W2485081618 cites W4244424013 @default.
• W2485081618 doi "https://doi.org/10.1155/2016/4526578" @default.
• W2485081618 hasPublicationYear "2016" @default.
• W2485081618 type Work @default.
• W2485081618 sameAs 2485081618 @default.
• W2485081618 citedByCount "1" @default.
• W2485081618 countsByYear W24850816182020 @default.
• W2485081618 crossrefType "journal-article" @default.
• W2485081618 hasAuthorship W2485081618A5001512863 @default.
• W2485081618 hasAuthorship W2485081618A5037010369 @default.
• W2485081618 hasAuthorship W2485081618A5043179374 @default.
• W2485081618 hasAuthorship W2485081618A5047258036 @default.
• W2485081618 hasAuthorship W2485081618A5059444685 @default.
• W2485081618 hasBestOaLocation W24850816181 @default.
• W2485081618 hasConcept C121332964 @default.
• W2485081618 hasConcept C147789679 @default.
• W2485081618 hasConcept C148898269 @default.
• W2485081618 hasConcept C155647269 @default.
• W2485081618 hasConcept C161790260 @default.
• W2485081618 hasConcept C175113610 @default.
• W2485081618 hasConcept C178790620 @default.
• W2485081618 hasConcept C179104552 @default.
• W2485081618 hasConcept C184651966 @default.
• W2485081618 hasConcept C185592680 @default.
• W2485081618 hasConcept C187428577 @default.
• W2485081618 hasConcept C2775885272 @default.
• W2485081618 hasConcept C2776211377 @default.
• W2485081618 hasConcept C2776304896 @default.
• W2485081618 hasConcept C2777768854 @default.
• W2485081618 hasConcept C2780349576 @default.
• W2485081618 hasConcept C521977710 @default.
• W2485081618 hasConcept C55904794 @default.
• W2485081618 hasConcept C62520636 @default.
• W2485081618 hasConcept C65024703 @default.
• W2485081618 hasConcept C75473681 @default.
• W2485081618 hasConcept C93391505 @default.
• W2485081618 hasConceptScore W2485081618C121332964 @default.
• W2485081618 hasConceptScore W2485081618C147789679 @default.
• W2485081618 hasConceptScore W2485081618C148898269 @default.
• W2485081618 hasConceptScore W2485081618C155647269 @default.
• W2485081618 hasConceptScore W2485081618C161790260 @default.
• W2485081618 hasConceptScore W2485081618C175113610 @default.
• W2485081618 hasConceptScore W2485081618C178790620 @default.
• W2485081618 hasConceptScore W2485081618C179104552 @default.
• W2485081618 hasConceptScore W2485081618C184651966 @default.
• W2485081618 hasConceptScore W2485081618C185592680 @default.
• W2485081618 hasConceptScore W2485081618C187428577 @default.
• W2485081618 hasConceptScore W2485081618C2775885272 @default.
• W2485081618 hasConceptScore W2485081618C2776211377 @default.
• W2485081618 hasConceptScore W2485081618C2776304896 @default.
• W2485081618 hasConceptScore W2485081618C2777768854 @default.
• W2485081618 hasConceptScore W2485081618C2780349576 @default.
• W2485081618 hasConceptScore W2485081618C521977710 @default.
• W2485081618 hasConceptScore W2485081618C55904794 @default.
• W2485081618 hasConceptScore W2485081618C62520636 @default.
• W2485081618 hasConceptScore W2485081618C65024703 @default.
• W2485081618 hasConceptScore W2485081618C75473681 @default.
• W2485081618 hasConceptScore W2485081618C93391505 @default.

• next