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- W2485719998 abstract "Publisher Summary The principal application of polymer blends is in the manufacture of fracture-resistant plastics, a fact that testifies to the practical importance of fracture properties to the user of plastics products. The fracture resistance of polystyrene can be increased substantially by adding a small proportion of rubber to obtain high-impact polystyrene (HIPS). This chapter describes general features of a variety of rubber-toughened plastics and the relationship between structure and fracture resistance. Study of rubber-toughened plastics shows that phase separation is an essential feature in which the rubber must be dispersed randomly like small discrete particles in the continuous-matrix phase. Other necessary features of the rubber phase are: (a) low shear modulus in relation to the matrix polymer; (b) good adhesion to the matrix; (c) adequate cross-linking; (d) average particle diameter near the optimum value for the material; and (e) low glass transition temperature. The chapter also highlights principles of fracture mechanics that begins with the assumption that all materials contain intrinsic cracks, flaws, and other defects. Four important techniques have been developed for studying rubber toughening. Each technique is capable of yielding quantitative information, therefore, placing the subject on a proper scientific foundation. The techniques are osmium staining, scanning electron microscopy, volumetric strain measurement, and fracture mechanics." @default.
- W2485719998 created "2016-08-23" @default.
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- W2485719998 date "1978-01-01" @default.
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- W2485719998 title "Fracture Phenomena in Polymer Blends" @default.
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- W2485719998 doi "https://doi.org/10.1016/b978-0-12-546802-2.50010-5" @default.
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