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- W2485736963 abstract "Homo - and heterocontacts of organic conductor β-(BEDT-TTF)2I3 and [(C2H5)4N]0.5[Ni(dmit)2] were investigated at 4.2 K. The I-V characteristics of the contacts and their first dV/dI(V) and second derivatives d2V/dI2 (V) (point-contact spectra) were measured in the voltage range 0-250mV. The experiments for contacts oriented in different crystallografic directions were carried out. The spectra measured on contacts with the current flow in the plane of the organic molecule layers display features caused by the interaction between the electrons and intramolecular vibrations. The spectra of the samples with the axis perpendicular to the BEDT-TTF layers have maxima reflecting the predominating contribution of the anion I3 to the scattering of charge carriers in such point contacts. So, the interaction of electrons with intramolecular vibrations of organic conductors was demonstrated directly. Point-contact spectra of layered organic conductors were shown to be essentially anisotropic. The transition to heterojunctions with a superconducting inclusion is observed at T=4.2K with increasing confining force between the electrodes. The values of the energy gap for the organic superconductor and the excess current of the heterocontacts were calculated. The relation between the intensity of the electron-vibrational interaction and conducting properties of the materials under investigation was obtained. The criterion for the synthesis of new organic superconductor is discussed." @default.
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- W2485736963 date "1999-07-23" @default.
- W2485736963 modified "2023-10-13" @default.
- W2485736963 title "Point Contact Spectroscopy of Organic Conductors" @default.
- W2485736963 doi "https://doi.org/10.1021/bk-1999-0730.ch014" @default.
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