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- W2486242941 abstract "Ammonolysis of aliphatic and aromatic polycarbonates in liquid or in supercritical ammonia has been studied. Reaction products are alcohols (phenols) and urea. Ammonolysis of bisphenol A polycarbonate (BPA-PC) proceeds at room temperature at a high rate depending on the size and surface of particles. BPA-PC in composites like compact discs or car windows, consisting of a sandwich of glass layers bounded with a polyurethane adhesive to a polycarbonate, can be selectively ammonolyzed. Aliphatic poly(1,6-hexanediyl carbonate) can be fractionated without ammonolytic degradation in liquid ammonia up to 100 °C while ammonolysis occurs under supercritical conditions. If residence time and temperature (rate of reaction) are properly adjusted controlled degradation to oligomers is possible." @default.
- W2486242941 created "2016-08-23" @default.
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- W2486242941 date "2005-03-08" @default.
- W2486242941 modified "2023-10-03" @default.
- W2486242941 title "Ammonolysis of Polycarbonates with (Supercritical) Ammonia: An alternative for Chemical Recycling" @default.
- W2486242941 doi "https://doi.org/10.1021/bk-2005-0898.ch018" @default.
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