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- W2486705037 abstract "Fullerene chemistry has become a very active research field, largely because of the uniqueness of the C60 molecule and the variety of fullerene derivatives that appear to be possible. Chemists have learned how to generate a diverse group of fullerene derivatives, where molecular fragments are bonded to the C60cage, leaving the cage essentially intact, although the C-C bond lengths in the vicinity of the attachment are perturbed. Many of these chemical reactions have taken advantage of the electrophilic properties of fullerenes, that is, their tendency to attract electrons. Because all the carbon bonds in the fullerene molecule are satisfied within the molecular shell, substitution reactions involving the exchange of one chemical group for another, as is common in organic chemistry, are not possible, although substitution of boron for carbon in the shell has been observed in molecular beam experiments. Furthermore, catastrophic decomposition of the carbon shell occurs in oxygen above 400ºC." @default.
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- W2486705037 date "1996-01-01" @default.
- W2486705037 modified "2023-10-18" @default.
- W2486705037 title "Fullerene Chemistry and Electrochemistry" @default.
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- W2486705037 doi "https://doi.org/10.1016/b978-012221820-0/50010-1" @default.
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