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- W2486809785 startingPage "585" @default.
- W2486809785 abstract "Most pure substances have a definite melting temperature below which the change from a random liquid structure to a well ordered, periodic crystalline structure can occur; this transformation is called crystallization; the reverse process is called melting. The crystallization of polymers depends on the possibilities of nucleation and growth. This chapter represents the structural regularity of the polymer that has a profound influence on both. Correlations were found for estimating the rate of spherulitic crystallization. Apart from this normal mode of bulk crystallization, other modes are frequently observed: induced crystallization by pressure and stress and extended chain crystallization. The latter mode occurs under special conditions for flexible chain polymers but is the normal mode for rigid chain polymers. Crystallization is also possible from solutions; the reverse process is called dissolving. Crystallization from a solution largely depends on the rate of cooling and on the rate of change in solubility connected with it. Again, the polymers with a regular molecular chain without side groups crystallize fast." @default.
- W2486809785 created "2016-08-23" @default.
- W2486809785 creator A5003679221 @default.
- W2486809785 date "1997-01-01" @default.
- W2486809785 modified "2023-09-25" @default.
- W2486809785 title "CRYSTALLIZATION AND RECRYSTALLIZATION" @default.
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- W2486809785 doi "https://doi.org/10.1016/b978-0-444-82877-4.50026-3" @default.
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