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- W2486859980 abstract "Methylammonium trichloromercurate (II) (CH 3 NH 3 HgCl 3 ) single crystals have been grown by slow evaporation method at room temperature. The crystals obtained are colourless, bright, transparent and square-shaped plateletswith an average size of 5×1.5×0.3 cm. The grown crystals have been characterized through elemental analysis, powder XRD, thermogravimetry (TG), differential scanning calorimetry (DSC), FTIR and NMR spectroscopic techniques. The elemental analysis confirms the molecular formula of the title compound. The crystallinity of the synthesized compound is evident from well-defined and sharp Bragg peaks obtained in the powder XRD pattern. The decomposition pattern of the compound is formulated using the TG. Thermal anomalies observed in the DSC curves at 0.6 and -15.9 °C during the heating and cooling cycles are indicative of first-order structural phase transition in the crystal. The FTIR and far IR spectra show the characteristic absorption bands due to CH 3 NH 3 + and HgCl 3 - ions. The NMR spectrum indicates the presence of only one kind of chemically and magnetically equivalent protons of the methyl group present in the compound." @default.
- W2486859980 created "2016-08-23" @default.
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- W2486859980 date "2003-10-01" @default.
- W2486859980 modified "2023-09-23" @default.
- W2486859980 title "Infrared and thermal studies in methylammonium trichloromercurate (II) single crystals" @default.
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