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- W2487013088 abstract "Moving further away from equilibrium, one gets different types of dissipative structures involving time order and space order. This chapter is concerned with time order involving chemical oscillations. Around 1968, the credibility of the Belousov–Zhabotinskii reaction involving the reactants BrO 3− , Ce 4+ , malonic acid, and H 2 SO 4 was well established after the discovery of Brusselator model. This triggered detailed investigations on similar oscillatory reactions in order to have a reliable picture of the mechanism. This initiated use of nonlinear kinetics and computer modeling with the result of insight into the mechanism. The mechanism involved the concept of positive and negative feedback through autocatalysis and inhibitory reactions. Oscillatory reactions are a typical class of phenomena, which display unusual features. After the discovery of the Belousov–Zhabotinskii (B–Z) reaction, there has been a tremendous flurry of activity and a large number of such reactions have been discovered during recent years. Biochemical reactions such as glycolytic oscillations and peroxidase catalyzed oxidation of nicotinamide adenosine deoxyhydrogenase (NADH) have also generated considerable interest. The interest in such reactions is still sustained in view of their importance in understanding cardiac and neuronal oscillations. In the case of many oscillatory chemical reactions, detailed reaction mechanisms have been postulated and verified with the help of numerical computation. This has also been particularly so for B–Z reaction where the Field–Koros–Noyes mechanism has been invoked." @default.
- W2487013088 created "2016-08-23" @default.
- W2487013088 creator A5016059682 @default.
- W2487013088 date "2008-01-01" @default.
- W2487013088 modified "2023-09-27" @default.
- W2487013088 title "TIME ORDER – CHEMICAL OSCILLATIONS" @default.
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- W2487013088 doi "https://doi.org/10.1016/b978-044452188-0.50011-2" @default.
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