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• W2487267095 endingPage "391" @default.
• W2487267095 startingPage "369" @default.
• W2487267095 abstract "Aryl halides have an important role in photochemistry since a long time. Historically, studies of the phosphorescence of aromatics and of their halogenated derivatives have been instrumental in dening the modern concept of triplet state, and both the intersystem crossing [1] and the fragmentation of phenyl halides have been long known [2]. In the early years of these studies, attention was given more oen to photophysics than to photochemistry. is is because the introduction of electron-withdrawing substituents, such as halogen atoms, in the ring further increases the already high stability of aromatic compounds, both in the ground and excited states. Indeed, many aromatic compounds are quite photostable and the absorption of a photon leads to reemission rather than to reaction, since excitation causes only a partial decrease of the bonding character in the multiple π-electron array of such compounds and the rigid σ-bond skeleton disfavors geometric modications. Indeed, stability to chemical agents and to irradiation is characteristic of many aryl halides, and this family includes some notoriously persistent environmental pollutants, such as DDT and polychlorobiphenyls. However, photochemistry, albeit oen ine‚cient, is one of the few available paths for the degradation of such compounds and thus this is16.1 Introduction 36916.2 E‡ect of Halide Substituents on the PhotophysicalParameters of Aromatics 37016.3 General Scheme of Photoreactivity 37216.4 Photochemical Reactions Not Involving16.7 ArSN2* Substitution Reactions 38216.8 ArSN1 Arylation Reactions 38216.9 Application to Depollution 386" @default.
• W2487267095 created "2016-08-23" @default.
• W2487267095 creator A5022014352 @default.
• W2487267095 creator A5061398027 @default.
• W2487267095 date "2012-03-21" @default.
• W2487267095 modified "2023-10-16" @default.
• W2487267095 title "Photochemistry of Aryl Halides" @default.
• W2487267095 cites W1964769482 @default.
• W2487267095 cites W1967039254 @default.
• W2487267095 cites W1969066912 @default.
• W2487267095 cites W1969382692 @default.
• W2487267095 cites W1972077088 @default.
• W2487267095 cites W1972416754 @default.
• W2487267095 cites W1973060163 @default.
• W2487267095 cites W1979607904 @default.
• W2487267095 cites W1980123376 @default.
• W2487267095 cites W1981645268 @default.
• W2487267095 cites W1985851029 @default.
• W2487267095 cites W1992445870 @default.
• W2487267095 cites W2002922795 @default.
• W2487267095 cites W2003554306 @default.
• W2487267095 cites W2004596096 @default.
• W2487267095 cites W2004637227 @default.
• W2487267095 cites W2004779786 @default.
• W2487267095 cites W2010947493 @default.
• W2487267095 cites W2011734752 @default.
• W2487267095 cites W2012727893 @default.
• W2487267095 cites W2013678044 @default.
• W2487267095 cites W2014672413 @default.
• W2487267095 cites W2019872051 @default.
• W2487267095 cites W2020440798 @default.
• W2487267095 cites W2020659146 @default.
• W2487267095 cites W2021511649 @default.
• W2487267095 cites W2023707806 @default.
• W2487267095 cites W2027012527 @default.
• W2487267095 cites W2027825885 @default.
• W2487267095 cites W2027943847 @default.
• W2487267095 cites W2028077247 @default.
• W2487267095 cites W2030462125 @default.
• W2487267095 cites W2038014804 @default.
• W2487267095 cites W2039122216 @default.
• W2487267095 cites W2039151179 @default.
• W2487267095 cites W2040515996 @default.
• W2487267095 cites W2041077468 @default.
• W2487267095 cites W2047601092 @default.
• W2487267095 cites W2052134019 @default.
• W2487267095 cites W2052954631 @default.
• W2487267095 cites W2055401709 @default.
• W2487267095 cites W2062952102 @default.
• W2487267095 cites W2063680538 @default.
• W2487267095 cites W2064174504 @default.
• W2487267095 cites W2064652012 @default.
• W2487267095 cites W2067064962 @default.
• W2487267095 cites W2069979811 @default.
• W2487267095 cites W2073099612 @default.
• W2487267095 cites W2074623021 @default.
• W2487267095 cites W2075348883 @default.
• W2487267095 cites W2075352486 @default.
• W2487267095 cites W2081337980 @default.
• W2487267095 cites W2081725252 @default.
• W2487267095 cites W2083394995 @default.
• W2487267095 cites W2083610670 @default.
• W2487267095 cites W2083903328 @default.
• W2487267095 cites W2085617237 @default.
• W2487267095 cites W2087352208 @default.
• W2487267095 cites W2089683972 @default.
• W2487267095 cites W2089966653 @default.
• W2487267095 cites W2091318744 @default.
• W2487267095 cites W2092371355 @default.
• W2487267095 cites W2093836863 @default.
• W2487267095 cites W2108544914 @default.
• W2487267095 cites W2111105750 @default.
• W2487267095 cites W2114316628 @default.
• W2487267095 cites W2121037596 @default.
• W2487267095 cites W2123311219 @default.
• W2487267095 cites W2143546017 @default.
• W2487267095 cites W2149878175 @default.
• W2487267095 cites W2151060953 @default.
• W2487267095 cites W2164536568 @default.
• W2487267095 cites W2170821282 @default.
• W2487267095 cites W2171654486 @default.
• W2487267095 cites W2319856394 @default.
• W2487267095 cites W2336850845 @default.
• W2487267095 cites W2343978948 @default.
• W2487267095 cites W2949855946 @default.
• W2487267095 cites W2950637581 @default.
• W2487267095 cites W2951344676 @default.
• W2487267095 cites W2951965589 @default.
• W2487267095 cites W2952023329 @default.
• W2487267095 cites W2952145974 @default.
• W2487267095 cites W2952582208 @default.
• W2487267095 cites W4237567951 @default.
• W2487267095 cites W748392247 @default.
• W2487267095 cites W1986026007 @default.
• W2487267095 cites W2005404848 @default.
• W2487267095 doi "https://doi.org/10.1201/b12252-17" @default.
• W2487267095 hasPublicationYear "2012" @default.
• W2487267095 type Work @default.

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