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• W2487304416 endingPage "7842" @default.
• W2487304416 startingPage "7835" @default.
• W2487304416 abstract "A partially fluorinated, angular tetracarboxylic acid linker (H4L) incorporating a pendant amine moiety forms a three-dimensional Zn(II) framework, 1. The structure consists of paddle-wheel Zn2(CO2)4 secondary building units (SBUs) and Zn12(CO2)24 supramolecular building blocks (SBBs). Thermal stability of 1 is found to be low. However, it undergoes transmetalation reaction with Cu(II) at room temperature without losing crystallinity affording an isostructural framework, 1Cu. Framework 1Cu is thermally robust and allows generation of the solvent-free porous framework 1Cu′ upon activation with coordinatively unsaturated metal centers. Framework 1Cu′ exhibits water stability and at 77 K, adsorbs 2.56 wt % of H2 up to 1 bar that significantly increases to 4.01 wt % at 13 bar. Also, this framework gives a high adsorption of 164.70 cc/g of CH4 (11.7 wt %) at 303 K and 60 bar. The channel surfaces decorated with −NH2 group and unsaturated metal centers in 1Cu′ allow a promising 36.4 wt % of CO2 adsorption at 1 bar and 273 K. Moreover, it exhibits pronounced selectivity of CO2 adsorption over N2 and H2 at 273 K. Finally, the versatility of 1Cu′ is shown by its excellent heterogeneous catalytic activity in the Biginelli coupling reactions involving an aldehyde, urea, and ethylacetoacetate to afford dihydroprimidinones." @default.
• W2487304416 created "2016-08-23" @default.
• W2487304416 creator A5019478816 @default.
• W2487304416 creator A5019742512 @default.
• W2487304416 creator A5029384299 @default.
• W2487304416 creator A5053486645 @default.
• W2487304416 creator A5054602608 @default.
• W2487304416 date "2016-07-26" @default.
• W2487304416 modified "2023-10-18" @default.
• W2487304416 title "A Partially Fluorinated, Water-Stable Cu(II)–MOF Derived via Transmetalation: Significant Gas Adsorption with High CO₂ Selectivity and Catalysis of Biginelli Reactions" @default.
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• W2487304416 doi "https://doi.org/10.1021/acs.inorgchem.6b00154" @default.
• W2487304416 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27459252" @default.
• W2487304416 hasPublicationYear "2016" @default.
• W2487304416 type Work @default.

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