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- W24873105 abstract "An apparatus for adsorption microcalorimetry at low temperature under high-pressure conditions was set up. Adsorption isotherms and differential energy of adsorption of hydrogen on activated carbon fibers ACF of different pore widths and single-wall carbon nanotube SWNT were measured in the range of equilibrium pressure from 0 to 10 MPa at isothermal condition, 203, 223, 243, and 298 K. The adsorption capacity of hydrogen depended upon adsorption temperature and micropore size of ACF: the ACF with narrower pore size (pore diameter: 0.5 nm) exhibited higher sorption capacity than that with wider pore size (1.7 nm), and the uptakes at lower temperature were higher than those at higher temperature. The SWNT showed the highest adsorption uptakes among the samples. The differential energy of adsorption was calorimetrically evaluated as -10 ∼ -5 kJ/mol, which well agreed with the isosteric enthalpy of adsorption evaluated by Clausius-Clapeyron equation." @default.
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- W24873105 date "2007-01-01" @default.
- W24873105 modified "2023-09-24" @default.
- W24873105 title "Microcalorimetric Characterization of Hydrogen Adsorption on Nanoporous Carbon Materials" @default.
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- W24873105 doi "https://doi.org/10.1016/s0167-2991(07)80017-6" @default.
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