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- W2487313876 abstract "Milled rigid sheets of poly(vinyl chloride) on heating at 185°C. lose weight at a rate which increases with time. By polymer fractionation procedures, it was shown the rate of hydrogen chloride loss increases as the content of tetrahydrofuran-insoluble resin increases. The insoluble resin content accumulates at a rate which depends, in part, on the additive present. This insolubilization reaction is catalyzed by cadmium compounds. The increased dehydrochlorination rate of the insoluble crosslinked resins may result from the susceptibility of the crosslinked structures to oxidation and from the subsequent thermal degradation of the oxidation products. The effects of various common additives on the rates of insolubilization and weight loss are described." @default.
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- W2487313876 date "1968-06-01" @default.
- W2487313876 modified "2023-10-10" @default.
- W2487313876 title "The Control of Thermal Degradation Pathways in Poly(vinyl chloride) by Heat-Stabilizing Additives" @default.
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- W2487313876 doi "https://doi.org/10.1021/ba-1968-0085.ch002" @default.
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