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- W2487864618 abstract "The object of this paper is to review a general procedure (1) that allows the molecular weight distribution (MWD) of the polymer produced in an emulsion polymerization to be predicted with considerable generality. The theory to be presented permits the following microscopic kinetic processes to be comprehended: (i) the entry of free radicals into the latex particles from the continuous phase; (ii) the exit (or desorption) of free radicals from the particles; (iv) chain transfer, whether to monomer or added chain transfer agent; (v) bimolecular termination, whether by combination and/or disproportionation. The procedure allows all of these kinetic events to be acting simultaneously. It could be readily extended to encompass the effects of retarders. Chain transfer to polymer, which may be important in some industrial emulsion polymerizations and which results in long chain branching, is specifically excluded from the present treatment, although an extension of the theory should permit this" @default.
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- W2487864618 date "1981-10-07" @default.
- W2487864618 modified "2023-10-09" @default.
- W2487864618 title "The Molecular Weight Distributions of Emulsion Polymers" @default.
- W2487864618 doi "https://doi.org/10.1021/bk-1981-0165.ch005" @default.
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