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- W2487947324 abstract "This chapter discusses the methods used to grow single crystals and thin solid films of van der Waals-bonded C60 and C70. In principle, the methods described here can also be used for higher-mass fullerenes, if they can be isolated in sufficient quantity. Although crystalline fullerene material can be obtained by solution growth in saturated solvents, this method for growing pristine (undoped) fullerene films or crystals often leads to trapped solvent in the lattice. The low sublimation temperatures of C60and C70 allow vapor growth methods to be applied to both film and single crystal growth. Careful studies of C60 film growth have been made, and several substrates have been found which promote epitaxy in monolayer and thicker films. The photochemical transformation of solid C60 into what appears to be a polymeric solid in which the C60 shells remain intact but are tightly coupled to neighboring C60 molecules by intermolecular C-C bonds." @default.
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- W2487947324 date "1996-01-01" @default.
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- W2487947324 title "Single-Crystal and Epitaxial Film Growth" @default.
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- W2487947324 doi "https://doi.org/10.1016/b978-012221820-0/50009-5" @default.
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