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• W2487974543 abstract "Several novel chiral tridentate ligands containing thiazoline were efficiently synthesized from commercially available l=cysteine in high yield. These ligands were subsequently applied to the asymmetric Henry reaction of nitromethane and various aldehydes. It was found that the structures of the thiazoline ligands had a significant influence on the enantioselectivity. It was shown that the optimal catalyst for this reaction was a ligand complexed with CuCl, which was formed from chiral thiazoline with chiral aminoalcohol. At −20°C, with 10 mol% of this ligand, a product with (S)-configuration was isolated in 93% yield and 98% enantiomeric excess. Copyright © 2015 John Wiley & Sons, Ltd." @default.
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• W2487974543 date "2015-07-14" @default.
• W2487974543 modified "2023-10-08" @default.
• W2487974543 title "Synthesis and applications in Henry reactions of novel chiral thiazoline tridentate ligands" @default.
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• W2487974543 doi "https://doi.org/10.1002/aoc.3347" @default.
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