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- W2488114108 abstract "M r=972.39, monoclinic, P21/c, a= 10.861 (4), b= 19.916 (6), c=9-075 (4),~, ~'= 94.15 (5) °, U = 1958 ~3 Z = 2, D x = 1.649 Mg m -3, 2(Mo Kct) = 0.71069 ,~,, g = 1.56 mm -I, F(000) = 972, T= 294 (1)K. Final R = 0.032 for 2727 unique observed X-ray diffractometer data. Two only slightly distorted trigonal-bipyramidal units (~-O)-SbPh3-O- S(O2)C2H4OH with O atoms in apical and C(phenyl) atoms in equatorial positions are linked via a linear Sb-O-Sb bridge. The Sb-~-O bond of 1.936 (1)A is rather short. The Sb-O bond to the unidentately coordinated sulfonate group I2.276 (4)~1 appears to have appreciably high ionic character. Introduction. The chemistry of triorgano-Group V element sulfonates is rather unexplored and structures of such compounds are unknown. We recently obtained for the first time, by reaction of Ph3SbO (Ph = C6H 5) with sulfonic acids in different solvents, antimony compounds which correspond to the formula (Ph3SbO3SR)20 (HOsSR = sulfonic acid) having, ac- cording to spectroscopic data, an Sb-O-Sb bridge. Compounds of the type (R3SbX)20 (R = organogroup, X = anionic ligand) may have a bent Sb-O-Sb bridge, as in (Ph3SbN3)20 (Sb-O-Sb:139.8 °, Ferguson & Ridley, 1973), or a linear bridge as in (Ph3SbOOC4H9)20 (Starikova, Shchegoleva, Trunov & Pokrovskaya, 1978). To obtain more facts about influences which determine the type of bridge in distiboxane and also to learn more about the coor-" @default.
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- W2488114108 date "1985-01-01" @default.
- W2488114108 modified "2023-09-27" @default.
- W2488114108 title "Structure ofg-Oxo-bis((2-hydroxyethanesulfonato)triphenylantimony(V))," @default.
- W2488114108 hasPublicationYear "1985" @default.
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