Matches in SemOpenAlex for { <https://semopenalex.org/work/W2488187510> ?p ?o ?g. }
- W2488187510 endingPage "23811" @default.
- W2488187510 startingPage "23803" @default.
- W2488187510 abstract "Chiroptical spectroscopy of lanthanides sensitively reflects their environment and finds various applications including probing protein structures. However, the measurement is often hampered by instrumental detection limits. In the present study circularly polarized luminescence (CPL) of a europium complex induced by amino acids is monitored by Raman optical activity (ROA) spectroscopy, which enables us to detect weak CPL bands invisible to conventional CPL spectrometers. In detail, the spectroscopic response to the protonation state could be studied, e.g. histidine at pH = 2 showed an opposite sign of the strongest CPL band in contrast to that at pH = 7. The spectra were interpreted qualitatively on the basis of the ligand-field theory and related to CPL induced by an external magnetic field. Free energy profiles obtained by molecular dynamic simulations for differently charged alanine and histidine forms are in qualitative agreement with the spectroscopic data. The sensitivity and specificity of the detection promise future applications in probing peptide and protein side chains, chemical imaging and medical diagnosis. This potential is observed for human milk and hen egg-white lysozymes; these proteins have a similar structure, but very different induced CPL spectra." @default.
- W2488187510 created "2016-08-23" @default.
- W2488187510 creator A5015227401 @default.
- W2488187510 creator A5067364493 @default.
- W2488187510 creator A5085121636 @default.
- W2488187510 date "2016-01-01" @default.
- W2488187510 modified "2023-10-12" @default.
- W2488187510 title "Chiral sensing of amino acids and proteins chelating with EuIII complexes by Raman optical activity spectroscopy" @default.
- W2488187510 cites W1971053045 @default.
- W2488187510 cites W1973905639 @default.
- W2488187510 cites W1976499671 @default.
- W2488187510 cites W1978034319 @default.
- W2488187510 cites W1979463580 @default.
- W2488187510 cites W1981029997 @default.
- W2488187510 cites W1984052681 @default.
- W2488187510 cites W1991474543 @default.
- W2488187510 cites W1995041523 @default.
- W2488187510 cites W2000236686 @default.
- W2488187510 cites W2002962460 @default.
- W2488187510 cites W2008281801 @default.
- W2488187510 cites W2009880568 @default.
- W2488187510 cites W2029352676 @default.
- W2488187510 cites W2032403535 @default.
- W2488187510 cites W2053845427 @default.
- W2488187510 cites W2059340298 @default.
- W2488187510 cites W2063571966 @default.
- W2488187510 cites W2073328513 @default.
- W2488187510 cites W2073623394 @default.
- W2488187510 cites W2077808334 @default.
- W2488187510 cites W2081318221 @default.
- W2488187510 cites W2081535184 @default.
- W2488187510 cites W2083799287 @default.
- W2488187510 cites W2085594997 @default.
- W2488187510 cites W2091063438 @default.
- W2488187510 cites W2093381148 @default.
- W2488187510 cites W2105704430 @default.
- W2488187510 cites W2107916342 @default.
- W2488187510 cites W2109410638 @default.
- W2488187510 cites W2112154906 @default.
- W2488187510 cites W2127119100 @default.
- W2488187510 cites W2138638170 @default.
- W2488187510 cites W2138956701 @default.
- W2488187510 cites W2142692985 @default.
- W2488187510 cites W2147486253 @default.
- W2488187510 cites W2147587163 @default.
- W2488187510 cites W2147993766 @default.
- W2488187510 cites W2160410910 @default.
- W2488187510 cites W2161040220 @default.
- W2488187510 cites W2161605421 @default.
- W2488187510 cites W2169924204 @default.
- W2488187510 cites W2186981075 @default.
- W2488187510 cites W2323288961 @default.
- W2488187510 cites W2326411711 @default.
- W2488187510 cites W2330374780 @default.
- W2488187510 cites W2332645972 @default.
- W2488187510 cites W2333536087 @default.
- W2488187510 cites W2334732464 @default.
- W2488187510 cites W2416733579 @default.
- W2488187510 cites W2419503320 @default.
- W2488187510 cites W2509128381 @default.
- W2488187510 cites W2951549793 @default.
- W2488187510 cites W3137609830 @default.
- W2488187510 cites W4211229119 @default.
- W2488187510 cites W4230737148 @default.
- W2488187510 doi "https://doi.org/10.1039/c6cp03968e" @default.
- W2488187510 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27549078" @default.
- W2488187510 hasPublicationYear "2016" @default.
- W2488187510 type Work @default.
- W2488187510 sameAs 2488187510 @default.
- W2488187510 citedByCount "38" @default.
- W2488187510 countsByYear W24881875102017 @default.
- W2488187510 countsByYear W24881875102018 @default.
- W2488187510 countsByYear W24881875102019 @default.
- W2488187510 countsByYear W24881875102020 @default.
- W2488187510 countsByYear W24881875102021 @default.
- W2488187510 countsByYear W24881875102022 @default.
- W2488187510 crossrefType "journal-article" @default.
- W2488187510 hasAuthorship W2488187510A5015227401 @default.
- W2488187510 hasAuthorship W2488187510A5067364493 @default.
- W2488187510 hasAuthorship W2488187510A5085121636 @default.
- W2488187510 hasBestOaLocation W24881875101 @default.
- W2488187510 hasConcept C113196181 @default.
- W2488187510 hasConcept C120665830 @default.
- W2488187510 hasConcept C121332964 @default.
- W2488187510 hasConcept C145148216 @default.
- W2488187510 hasConcept C148869448 @default.
- W2488187510 hasConcept C178790620 @default.
- W2488187510 hasConcept C185592680 @default.
- W2488187510 hasConcept C192562407 @default.
- W2488187510 hasConcept C2777634753 @default.
- W2488187510 hasConcept C2778460671 @default.
- W2488187510 hasConcept C2779856020 @default.
- W2488187510 hasConcept C30095370 @default.
- W2488187510 hasConcept C32891209 @default.
- W2488187510 hasConcept C32909587 @default.
- W2488187510 hasConcept C40003534 @default.
- W2488187510 hasConcept C49040817 @default.
- W2488187510 hasConcept C502696234 @default.