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- W2488210384 abstract "As recently as three years ago, many experts in molecular dynamics thought that chemical activation by means of infrared lasers was not likely to be both practical and useful. There were essentially two reasons for this view. (1) The kinds of reactions which it would be most useful to induce have relatively high activation energies, in the range of 50-120 kcal/mole. Such energies are considerably greater than those of individual infrared photons: at 1000 cm-1, hν is equivalent to only 2.86 kcal/mole; and there were reasons to doubt that the required many- photon absorption could take place even at high infrared intensities. (2) It makes no economic sense to use expensive infrared radiation rather than conventional burner heat unless the radiatively activated molecules react more efficiently or in a distinctive, more desirable manner. Yet there were reasons to fear that the absorbed infrared energy at all but very low" @default.
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- W2488210384 date "1977-06-01" @default.
- W2488210384 modified "2023-09-26" @default.
- W2488210384 title "Inter- and Intramolecular Energy Transfer Deduced from Macroscopic Infrared Laser Chemistry" @default.
- W2488210384 doi "https://doi.org/10.1021/bk-1977-0056.ch010" @default.
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