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• W2488343603 startingPage "201" @default.
• W2488343603 abstract "Solution-based approaches towards metal oxides are based on hydrolysis and condensation processes starting from precursor solutions. Metal oxido clusters represent important intermediates within these processes, and a detailed understanding of their (structural) chemistry adds to the knowledge about how to control structure, particle size, and morphology of the final hydrolysis products. The present review focuses on structural aspects of metal oxido clusters which are composed of more than ten metal atoms and contain at least one oxido ligand within the cluster structure, however where necessary smaller clusters and hydroxido clusters are also included. In addition to fully inorganic metal oxido clusters, those stabilized by organic ligands and in addition selected organometallic examples are also discussed. The group 13–15 elements Al, Ga, In, Ge, Sn, Pb, Sb, and Bi are considered in this review, complemented by some examples of Ce, U, and Pu. Large metal oxido clusters of the latter with diameters of about 2 nm show remarkable resemblance of their metal oxido core structures with those of bismuth, which is attributed to the fact that the trivalent and tetravalent metal oxides of these elements tend to form structures which can be deduced from the fluorite structure type. Intriguing examples are represented by various bismuth oxido clusters which exhibit a {Bi38O45} core structure, stabilized by a variety of ligands at the periphery. For gallium, two large metal oxido clusters have been reported which also show an interesting relationship to a parent gallium oxide, whereas for aluminum two tridecanuclear cluster types dominate the literature, the metal hydroxido clusters and cationic Keggin-type ions, neither of which is related to structures of aluminum oxide. However, the structural chemistry of the group 13–15 metal oxido clusters is quite different from the heteropolyanionic nature of polyoxometalates and compared to the latter is often less intensely addressed. Thus, the review provides an overview on the growing number of large group 13–15 metal oxido clusters including information on reported synthesis conditions, yields, and analytics." @default.
• W2488343603 created "2016-08-23" @default.
• W2488343603 creator A5090018109 @default.
• W2488343603 date "2016-01-01" @default.
• W2488343603 modified "2023-09-26" @default.
• W2488343603 title "Metal Oxido Clusters of Group 13–15 Elements" @default.
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