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- W2488408842 abstract "Anthracene-labeled poly(2-ethylhexyl methacrylate) copolymer latex particles containing carbodiimide groups and corresponding phenanthrene-labeled particles containing carboxylic acid groups were synthesized. We employed fluorescence energy transfer experiments to follow polymer diffusion rates in these films, and FTIR measurements to follow the carbodiimide group reaction rates. The -COOH- and -N=C=N-containing polymers have limited miscibility. During film formation from the aqueous dispersions at 22 °C some branched polymer is formed by the reaction of the carbodiimide and carboxylic acid groups. As the films are annealed, further reaction occurs, and polymer diffusion leads to full mixing of the two polymers. The formation of branches promotes polymer miscibility but retards the rate of polymer diffusion. While the rate of polymer diffusion at 60 °C is on the whole faster than the rate the chemical reaction between the -N=C=N- and -COOH groups, it is still substantially slower than the polymer diffusion rate in PEHMA latex films lacking the reactive groups." @default.
- W2488408842 created "2016-08-23" @default.
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- W2488408842 date "2001-07-26" @default.
- W2488408842 modified "2023-09-25" @default.
- W2488408842 title "Film Formation from Blends of Carbodiimide and Carboxylic Acid-Functional Latex" @default.
- W2488408842 doi "https://doi.org/10.1021/bk-2001-0790.ch005" @default.
- W2488408842 hasPublicationYear "2001" @default.
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