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- W2488444522 abstract "Amorphous poly(arylene ether sulfones) of controlled Mn were synthesized by step polymerization of bisphenol-A phenolate with activated aromatic halides in the presence of m-aminophenol. Utilization of the amino terminated polysulfones (NH2PSF) to co-cure with the diglycidyl ether of bisphenol A (DGEBA) and/or tetraglycidyl 4,4′-diaminodiphenylmethane (TGDDM) via thermal or microwave (EM) processing was conducted at temperatures of ∼190-240°C. 4,4′-Diaminodiphenylsulfone (DDS) was employed as the curing agent. The bismaleimide systems (Matrimid 5292 A/B) were thermally or electromagnetically crosslinked through free radical reactions of the maleimide groups at temperatures of ∼250°C. The influence of oligomer molecular weight on the thermal, mechanical, and morphological properties of the thermoplastic toughened epoxy networks were investigated by DSC, fracture toughness (KIC) and SEM. Microwave processing can dramatically enhance the rate of network formation in a variety of systems. Morphological structure in thermoplastic toughened thermosets can be controlled via the microwave power utilized. Non-reactive thermoplastics which contain even modestly polar groups (e.g., PEEK, polyimides, etc.) can also be rapidily melt processed." @default.
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- W2488444522 date "1991-11-12" @default.
- W2488444522 modified "2023-10-16" @default.
- W2488444522 title "Electromagnetic (Microwave) Radiation Effects on Terminally Reactive and Nonreactive Engineering Polymer Systems" @default.
- W2488444522 doi "https://doi.org/10.1021/bk-1991-0475.ch022" @default.
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