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- W2488572657 abstract "Novel penta- and hexacoordinate spiro- polysilconate and polygermylate ionomeric materials have been synthesized. These materials are representatives of a new family of hybrid organic-inorganic ionomeric materials that contain penta- and hexacovalent silicon and germanium atoms in the main chain of the polymer. The materials are air stable, non-hygroscopic, amorphous powders. The incorporation of the hypervalent silicon and germanium functionality has been verified by 29Si and 13C solid state and solution NMR, 1H solution NMR, IR, and elemental analysis. The materials are thermally stable to ∼325°C (TGA and DSC) and are of a non-porous nature (0.3-8.5 m2g-1) (BET, N2)." @default.
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- W2488572657 date "1995-03-21" @default.
- W2488572657 modified "2023-10-14" @default.
- W2488572657 title "Hypervalent Spiro Polysiliconate and Polygermylate Ionomers" @default.
- W2488572657 doi "https://doi.org/10.1021/bk-1995-0585.ch019" @default.
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