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- W2488578421 abstract "Mixed surfactant systems containing an anionic fluorocarbon surfactant (sodium perfluorooctanoate) and various types of hydrocarbon surfactants have been studied comprehensively by means of surface tension, H-1 NMR, and F-19 NMR. When both fluorocarbon and hydrocarbon surfactants are anionic, the systems show strong positive deviation from ideal behavior. If the chains are long so that their mutual phobicity is large enough, two types of micelles can coexist in the same solution for intermediate mole fractions of the fluorocarbon component. For an anionic fluorocarbon surfactant mixed with nonionic, zwitterionic, or cationic hydrocarbon surfactants, the systems deviate negatively from ideal behavior. These observations are interpreted in terms of different interactions between the head groups and the hydrophobic chains. The experimental cmc data are compared with calculated results." @default.
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- W2488578421 date "1992-09-08" @default.
- W2488578421 modified "2023-10-04" @default.
- W2488578421 title "Micellization in Mixed Fluorocarbon—Hydrocarbon Surfactant Systems" @default.
- W2488578421 doi "https://doi.org/10.1021/bk-1992-0501.ch015" @default.
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