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- W2488883233 abstract "The Onsager reciprocal relations (orr) are a postulate of a linear thermodynamic theory of irreversible processes. This postulate states roughly that the matrix of linear coefficients L between properly chosen flows J and forces X is symmetric, that is <math display='block'> <mrow> <msub> <mi>L</mi> <mrow> <mi>i</mi><mi>j</mi> </mrow> </msub> <mo>=</mo><msub> <mi>L</mi> <mrow> <mi>j</mi><mi>i</mi> </mrow> </msub> </mrow> </math> $${L_{ij}} = {L_{ji}}$$ The concept of proper choice has been criticised and will be briefly discussed. Many phenomena are linear in the normal ranges of force variables, such as diffusion, thermal diffusion, transport in electrolyte solutions, heat and electrical conduction in solids, electrokinetic effects, and thermogalvanomagnetic effects. Appropriate experimental evidence in these cases will be reviewed, including recent experiments. The conclusion is that the ORR are valid within acceptable error limits Workers in continuum mechanics are challenged to find by their rigorous methods the macroscopic origin of this fundamental symmetry principle." @default.
- W2488883233 created "2016-08-23" @default.
- W2488883233 creator A5026945931 @default.
- W2488883233 date "1973-01-01" @default.
- W2488883233 modified "2023-09-23" @default.
- W2488883233 title "The Onsager Relations; Experimental Evidence" @default.
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- W2488883233 doi "https://doi.org/10.1007/978-1-349-02235-9_10" @default.
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