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• W2488894109 abstract "A new and highly efficient polymer, postpolymerization, modification platform based on an inverse electron demand Diels–Alder reaction is reported. Well-defined polymers were synthesized from allyl glycidyl ether and glycidol by anionic ring-opening polymerization with postpolymerization modifications conducted with a number of tetrazine derivatives that carried functional groups spanning from carboxylates and esters to primary amines. Analysis of polymerization kinetics by real-time 1H NMR, and GPC revealed a rapid and high degree of side-chain conversion (>99%), with the generation of well-defined functional polymers, in both organic and aqueous solvents, without the need for additives or catalysts." @default.
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• W2488894109 date "2016-07-25" @default.
• W2488894109 modified "2023-10-03" @default.
• W2488894109 title "Tetrazine-Mediated Postpolymerization Modification" @default.
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• W2488894109 doi "https://doi.org/10.1021/acs.macromol.6b00867" @default.
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