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- W2489205903 abstract "Abstract The reaction of 4-thiazolecarboxylic acid (Htzc) and dimethyltin(IV) dichloride with NaOH in mixed MeOH-H 2 O solvent led to the formation of a new Sn(IV) complex (Me 2 Sn) 4 ( μ 3 -O) 2 (tzc) 4 ( 1 ). Its structure has been characterized by elemental analysis, IR spectroscopy and single crystal and powder X-ray diffraction. Single-crystal X-ray diffraction revealed that complex 1 crystallizes in the monoclinic P 2 1 / c space group with Z = 2 and has a tetranuclear structure with crystallographically imposed centrosymmetry. The as-synthesized complex 1 was found to be active toward the bulk solvent-free polymerization of glycolide, producing poly(glycolic acid) with a number-average molecular weight up to 55.5 kDa." @default.
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- W2489205903 date "2016-07-02" @default.
- W2489205903 modified "2023-10-14" @default.
- W2489205903 title "A tetranuclear Sn(IV) 4-thiazolecarboxylate complex: synthesis, structure and catalytic behavior in the bulk ring-opening polymerization of glycolide" @default.
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- W2489205903 doi "https://doi.org/10.1515/znb-2015-0211" @default.
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