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- W2489367655 abstract "Abstract Asphaltene precipitation from reservoir crudes has been modeled using liquid-liquid equilibrium; the precipitated heavy phase is assumed to be in the liquid state and to consist of only asphaltene and resin. The light liquid phase is assumed to consist of the monomers of all the components and the micelles. A thermodynamic micellization model and the Peng-Robinson equation of state (EOS) description of all monomers fully specify the thermodynamic equilibrium state. From the direct minimization of the Gibbs free energy of the liquid-liquid system, the composition and the amount of each of the phases are calculated. The above model is used to calculate precipitation from three different reservoir crudes. Once vapor-liquid equilibrium parameters are obtained, there is no further adjustment of the parameters of the EOS for precipitation calculations. The predictions from the thermodynamic micellization model are in good agreement with data. The effect of pressure, temperature and composition on precipitation is properly predicted by the model." @default.
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- W2489367655 date "1997-10-05" @default.
- W2489367655 modified "2023-10-17" @default.
- W2489367655 title "Thermodynamic Micellization Model for Asphaltene Precipitation from Reservoir Crudes at High Pressures and Temperatures" @default.
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- W2489367655 doi "https://doi.org/10.2118/38857-ms" @default.
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