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- W2489437257 abstract "The existence of Single-Wall C-Nanocones (SWNCs), especially nanohorns (SWNHs), and BC2N/Boron Nitride (BN) analogues in cluster form is discussed in solution in this chapter. Theories are developed based on models bundlet and droplet describing size-distribution function. The phenomena present unified explanation in bundlet in which free energy of (BC2N/BN-)SWNCs involved in cluster is combined from two parts: volume one proportional to the number of molecules n in cluster and surface one, to n1/2. Bundlet enables describing distribution function of (BC2N/BN-)SWNC clusters by size. From geometrical differences bundlet [(BC2N/BN-)SWNCs] and droplet (C60/B15C30N15/B30N30) predict dissimilar behaviours. Various disclination (BC2N/BN-)SWNCs are studied via energetic and structural analyses. Several (BC2N/BN-)SWNC's ends are studied that are different because of closing structure and arrangement type. Packing efficiencies and interaction-energy parameters of (BC2N/BN-)SWNCs/SWNHs are intermediate between C60/B15C30N15/B30N30 and (BC2N/BN-)Single-Wall C-Nanotube (SWNT) clusters: in-between behaviour is expected; however, properties of (BC2N/BN-)SWNCs, especially (BC2N/BN-)SWNHs, are calculated closer to (BC2N/BN-)SWNTs. Structural asymmetry in different (BC2N/BN-)SWNCs characterized by cone angle distinguishes properties of types: P2. BC2N/BN, especially species isoelectronic with C-analogues may be stable." @default.
- W2489437257 created "2016-08-23" @default.
- W2489437257 creator A5030577905 @default.
- W2489437257 creator A5034115402 @default.
- W2489437257 date "2014-01-01" @default.
- W2489437257 modified "2023-09-27" @default.
- W2489437257 title "Nanostructures Cluster Models in Solution" @default.
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