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- W2489734228 abstract "The addition of hydroxide ions to substituted benzaldehydes (ArCHO + OH- ⇆ ArCH(OH)O-) is used to establish J_ acidity scales in water-ethanol and water-DMSO mixtures containing sodium hydroxide as a base. The pK-values in such mixtures are linearly correlated with Hammett substituent constants. The independence of reaction constant ρ of solvent composition confirms that substituted benzaldehydes are suitable J_ indicators for hydroxide solutions in water-ethanol and water-DMSO mixtures. Dependence of J_ values on sodium hydroxide concentration is only slightly affected by ethanol up to 90 % and at a constant sodium hydroxide concentration shows only small increase between 90 and 98 % ethanol. J_ increases more with increasing DMSO concentration, but the effect is much smaller than that of DMSO on H_ values based on proton abstraction from aniline." @default.
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- W2489734228 date "1976-06-01" @default.
- W2489734228 modified "2023-09-26" @default.
- W2489734228 title "Acidity Functions in Solutions of Strong Bases in Mixed Solvents" @default.
- W2489734228 doi "https://doi.org/10.1021/ba-1976-0155.ch022" @default.
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