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• W2489910080 abstract "Conjugated organic polymers offer a highly tailorable set of optical and electronic properties and show promise for a wide range of technological applications including light-emitting devices and solar cells. A key challenge is to tune the HOMO and LUMO energies and the HOMO-LUMO gap for particular applications. Sequence control of monomer order offers the ability to alter these optoelectronic properties, rather than synthesis of complex monomers. A set of over 4,000 sequenced hexamers is studied using stastical data mining of semiempirical quantum chemical calculations and compared to simple particle-in-a-box and Hückel models. The results suggest that conjugated polymers can be effectively tuned by sequence and block-length control in addition to monomer design." @default.
• W2489910080 created "2016-08-23" @default.
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• W2489910080 date "2014-01-01" @default.
• W2489910080 modified "2023-09-26" @default.
• W2489910080 title "Sequence Matters: Determining the Sequence Effect of Electronic Structure Properties in π-Conjugated Polymers" @default.
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• W2489910080 doi "https://doi.org/10.1021/bk-2014-1170.ch025" @default.
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