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• W2489957181 abstract "The origin of enantioselectivity in the dirhodium-catalyzed [3 + 2]-cycloaddition of nitrone and vinyldiazoacetate has been investigated using dispersion-corrected density functional theory. Taking a more realistic account of bulky ligands in models of the dirhodium catalyst when investigating its catalytic behavior is crucial for describing the effects resulting from a high level of asymmetric induction. More than one active site can be located and the extra reactivity is provided by an electron-donation interaction between the substrate and an additional Rh2L4 catalyst." @default.
• W2489957181 created "2016-08-23" @default.
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• W2489957181 date "2016-08-09" @default.
• W2489957181 modified "2023-10-18" @default.
• W2489957181 title "How Dirhodium Catalyst Controls the Enantioselectivity of [3 + 2]-Cycloaddition between Nitrone and Vinyldiazoacetate: A Density Functional Theory Study" @default.
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• W2489957181 doi "https://doi.org/10.1021/acs.joc.6b01447" @default.
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