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- W2489957303 abstract "The formal dipolar behaviour of furan-2,3-diones is illustrated by their reaction with ethyl glyoxylate under Lewis basic activation uniquely, giving access to isotetronic derivatives. The Janus-type nature of the activated species, both nucleophilic and electrophilic is revealed by ring-opening of the starting ketolactone. An unexpected reversible side-reaction was identified by in situ monitoring." @default.
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- W2489957303 date "2016-09-01" @default.
- W2489957303 modified "2023-09-26" @default.
- W2489957303 title "Furan-2,3-diones as masked dipoles: synthesis of isotetronic acids and mechanistic considerations" @default.
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- W2489957303 doi "https://doi.org/10.1016/j.tet.2016.07.072" @default.
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