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- W2490122906 abstract "Fluorinated analogs for allylic diphosphate substrates are important tools for studying the chemical mechanisms of enzyme catalyzed prenyl transfer reactions. Syntheses were developed for a series of mono-, di-, and trifluoromethyl geranyl and farnesyl derivatives. Comparisons of the effects of fluorine substitutions on the rates of prenyl transfer with those of model displacement reactions indicated that the enzymatic transformations proceeded through highly electrophilic transition states. Prenyl transfer to weakly nucleophilic carbon-carbon double bond acceptors are stepwise, while those to more nucleophilic sulfhydryl acceptors appear to be enforced." @default.
- W2490122906 created "2016-08-23" @default.
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- W2490122906 date "1996-08-13" @default.
- W2490122906 modified "2023-09-27" @default.
- W2490122906 title "Mechanistic Studies of the Prenyl Transfer Reaction with Fluorinated Substrate Analogs" @default.
- W2490122906 doi "https://doi.org/10.1021/bk-1996-0639.ch012" @default.
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