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- W2491024295 abstract "Excited states of transition metal complexes are often quenched by electron donors or electron acceptors in redox processes that can involve efficient conversion of light energy into high energy products. We have examined ways to circumvent the energy-wasting back reactions by modification of the complex, quencher, and medium or by adding reactive substrates to intercept products generated by electron transfer. For oxidative quenching, a variety of substrates are rapidly oxidized by certain RuL33+ complexes such that RuL32+ is regenerated but Oxrcd survives. For reductive quenching processes a combination of relatively slow rates of back reaction and rapid reaction of Redox enables the isolation of the high energy RuL3+ as a stable but highly reactive product." @default.
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- W2491024295 date "1979-05-05" @default.
- W2491024295 modified "2023-09-25" @default.
- W2491024295 title "Scope and Applications of Light-Induced Electron-Transfer Reactions of Metal Complexes for Energy Conversion and Storage" @default.
- W2491024295 doi "https://doi.org/10.1021/ba-1979-0173.ch020" @default.
- W2491024295 hasPublicationYear "1979" @default.
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