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- W2491036211 abstract "It is not easy to obtain both enantiomers of non-charged chiral complexes in optically pure form. Chromatographic separation by the use of asymmetric adsorption on an optically active adsorbent(for example, quartz, starch and d-lactose etc.) has been regarded as almost the only means for this purpose. However, usually such procedures lead to partial separation of enantiomers. This is probably because asymmetric adsorption is every weak. To make matters worse, we do not know the stereochemistry of asymmetric adsorption, nor how to improve the efficiency of separation. We attempted to attack this problem by extending the technique and the ion association model for ion-exchange chromatography. Here, we describe the mechanism of chromatographic separation of enantiomers of facial and meridional tris(aminoacidato)cobalt(III) chelates (See Figure 1). Complete Resolution of fac-[Co(β-ala)3] The facial isomer of [Co(β-ala)3] has three carboxyl oxygen atoms in a triangular face of an octahedron and three amino groups in the" @default.
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- W2491036211 date "1980-05-27" @default.
- W2491036211 modified "2023-09-26" @default.
- W2491036211 title "Optical Resolution of Facial and Meridional Tris(aminoacidato)cobalt(III) Chelates by <i>d</i>-Tartrate and by Antimony <i>d</i>-Tartrate" @default.
- W2491036211 doi "https://doi.org/10.1021/bk-1980-0119.ch016" @default.
- W2491036211 hasPublicationYear "1980" @default.
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