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- W2491066054 endingPage "11295" @default.
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- W2491066054 abstract "Abstract The activation of π‐bonds in diynyl esters has been investigated by using soft and hard Lewis acids. In the case of the soft selenium Lewis acid PhSeCl, sequential activation of the alkyne bonds leads initially to an isocoumarin (1 equiv PhSeCl) and then to a tetracyclic conjugated structure with the isocoumarin subunit fused to a benzoselenopyran (3 equiv PhSeCl). Conversely, the reaction with the hard Lewis acidic borane B(C 6 F 5 ) 3 initiates a cascade reaction to yield a complex π‐conjugated system containing phthalide and indene subunits." @default.
- W2491066054 created "2016-08-23" @default.
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- W2491066054 date "2016-08-03" @default.
- W2491066054 modified "2023-10-07" @default.
- W2491066054 title "Contrasting Frustrated Lewis Pair Reactivity with Selenium‐ and Boron‐Based Lewis Acids" @default.
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- W2491066054 doi "https://doi.org/10.1002/anie.201605239" @default.
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