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- W2491667154 abstract "The chiral Ni II complex of Schiff base of (S)-2-N-(N-benzylprolyl)aminobenzophenone and 5- amino-4,5-dihydro-3-(2,4,6-trimethylphenyl)isoxazol-5-carboxylic acid (6) was prepared via the cycloaddition of chiral complex of Ni 5 with mesitonitrile oxide 1. The cycloaddition proceeded with complete regioselectivity to provide 5-substituted isoxazolines 6 and 7. The approach of the dipole takes place predominantly from the less sterically hindered side of dipolarophile 5, the diastereoisomers were formed in 96:4 ratio. The detailed structure of 6 was established by X-ray analysis." @default.
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- W2491667154 date "2006-05-17" @default.
- W2491667154 modified "2023-09-28" @default.
- W2491667154 title "The synthesis of chiral NiII complex of Schiff base of (S)-2-N-(N-benzylprolyl)aminobenzophenone and 5-amino-4,5-dihydro-3-(2,4,6-trimethylphenyl)isoxazol-5-carboxylic acid" @default.
- W2491667154 doi "https://doi.org/10.3998/ark.5550190.0007.509" @default.
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