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- W2491993207 abstract "A novel concept for a lithium-air cell is described in this chapter. A working cell consists of liquid electrodes separated by a solid Li-ion-conducting LTAP (Li, Ti, Al, PO4) electrolyte. Poly-aromatic hydrocarbon (PAH)-based lithium solvated electron solution (LiSES) served as the liquid anode. The LiSES’s conductivity depends on the amounts of dissolved metallic Li and the tetrahydrofuran organic solvent for the PAH. Temperature dependence study of the LiSES’s conductivity indicates a metallic behavior. Successful LiSES full cell discharges were achieved with two different cathode solutions: (1) an oxygen cathode utilizing an electrolyte containing 20% perfluorocarbons (PFC) and (2) an iodine/methanol solution. The solid-state electrolyte in form of glass ceramic membrane is crucial to the success of Li-SES-based battery. However, the general use of such electrolyte is still limited by its chemical stability when exposed to Li-SES. LiPON coating prepared by thin-film deposition has proved to be effective in enhancing the membrane’s chemical stability, thus making the Li-SES-based battery more practical. Carbon materials can be designed for the metal-air cathode to enhance the oxygen-reduction-reaction (ORR) kinetics. Moderate oxidation treatment of the graphitized carbon material provide adequate amount of defect sites to improve the ORR kinetics while still preserving the graphitic matrix with minimum change in carbon surface area. At high overpotentials the reaction is limited by the oxygen’s mass transport which can cause the carbon cathode’s premature passivation. PFCs are expected to improve lithium oxygen batteries’ performance due to the high O2 solvents. 1-methoxyheptafluoropropane, a PFC with ether functional group, was incorporated in ether based electrolytes and its performance was tested in a Li-O2 cell. PFC addition increases the discharge voltage together with the rate capability of Li-O2 cells. Investigations by Rotating Ring Disk Electrode (RRDE) showed that the addition of 5 vol.% PFC increases the electrolyte’s oxygen concentration by two folds without significant change to the oxygen’s diffusion coefficient." @default.
- W2491993207 created "2016-08-23" @default.
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- W2491993207 date "2015-01-01" @default.
- W2491993207 modified "2023-09-25" @default.
- W2491993207 title "Lithium-air batteries for medium- and large-scale energy storage" @default.
- W2491993207 cites W1664474894 @default.
- W2491993207 cites W1931187865 @default.
- W2491993207 cites W1965177090 @default.
- W2491993207 cites W1965849954 @default.
- W2491993207 cites W1966991977 @default.
- W2491993207 cites W1967224470 @default.
- W2491993207 cites W1969165141 @default.
- W2491993207 cites W1969366933 @default.
- W2491993207 cites W1969528836 @default.
- W2491993207 cites W1970125014 @default.
- W2491993207 cites W1970756243 @default.
- W2491993207 cites W1971101373 @default.
- W2491993207 cites W1971577949 @default.
- W2491993207 cites W1973616608 @default.
- W2491993207 cites W1973888530 @default.
- W2491993207 cites W1976877316 @default.
- W2491993207 cites W1977582041 @default.
- W2491993207 cites W1977590244 @default.
- W2491993207 cites W1978113302 @default.
- W2491993207 cites W1980146245 @default.
- W2491993207 cites W1983428172 @default.
- W2491993207 cites W1983819531 @default.
- W2491993207 cites W1984060337 @default.
- W2491993207 cites W1984878754 @default.
- W2491993207 cites W1985239528 @default.
- W2491993207 cites W1985327657 @default.
- W2491993207 cites W1986348475 @default.
- W2491993207 cites W1988222336 @default.
- W2491993207 cites W1993360176 @default.
- W2491993207 cites W1996762633 @default.
- W2491993207 cites W1996791140 @default.
- W2491993207 cites W1997613205 @default.
- W2491993207 cites W1998006588 @default.
- W2491993207 cites W1998932417 @default.
- W2491993207 cites W2001471563 @default.
- W2491993207 cites W2006233726 @default.
- W2491993207 cites W2012706564 @default.
- W2491993207 cites W2013846617 @default.
- W2491993207 cites W2015853658 @default.
- W2491993207 cites W2016130470 @default.
- W2491993207 cites W2017050993 @default.
- W2491993207 cites W2017120011 @default.
- W2491993207 cites W2019534764 @default.
- W2491993207 cites W2020303185 @default.
- W2491993207 cites W2022496506 @default.
- W2491993207 cites W2023665497 @default.
- W2491993207 cites W2024978032 @default.
- W2491993207 cites W2025142502 @default.
- W2491993207 cites W2026016112 @default.
- W2491993207 cites W2026331986 @default.
- W2491993207 cites W2028108858 @default.
- W2491993207 cites W2028963773 @default.
- W2491993207 cites W2032870862 @default.
- W2491993207 cites W2033337938 @default.
- W2491993207 cites W2033400465 @default.
- W2491993207 cites W2035360355 @default.
- W2491993207 cites W2035711423 @default.
- W2491993207 cites W2035745576 @default.
- W2491993207 cites W2036131960 @default.
- W2491993207 cites W2036772922 @default.
- W2491993207 cites W2038026789 @default.
- W2491993207 cites W2043713115 @default.
- W2491993207 cites W2044997702 @default.
- W2491993207 cites W2050070998 @default.
- W2491993207 cites W2052858398 @default.
- W2491993207 cites W2055621447 @default.
- W2491993207 cites W2055655412 @default.
- W2491993207 cites W2058272047 @default.
- W2491993207 cites W2058416470 @default.
- W2491993207 cites W2060142904 @default.
- W2491993207 cites W2060834880 @default.
- W2491993207 cites W2061680435 @default.
- W2491993207 cites W2063040771 @default.
- W2491993207 cites W2064332952 @default.
- W2491993207 cites W2065747817 @default.
- W2491993207 cites W2066931959 @default.
- W2491993207 cites W2068268527 @default.
- W2491993207 cites W2069466697 @default.
- W2491993207 cites W2069727353 @default.
- W2491993207 cites W2070262637 @default.
- W2491993207 cites W2070627555 @default.
- W2491993207 cites W2072931240 @default.
- W2491993207 cites W2074512160 @default.
- W2491993207 cites W2075574153 @default.
- W2491993207 cites W2075853414 @default.
- W2491993207 cites W2077670457 @default.
- W2491993207 cites W2084972376 @default.
- W2491993207 cites W2085055499 @default.