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- W2492046918 abstract "The technique of IR dichroism was used to characterize segmental orientation in several multicomponent polymer systems. Compatibility at the molecular level usually leads to similar segmental orientation of the blend components. In contrast, different orientation behavior is observed for components in those incompatible blends that exhibit large-scale phase separation. Orientation characteristics for the blends of poly(vinyl chloride) (PVC) with poly(ε-caprolactone) (PCL), PCL with nitrocellulose (NC), PVC with a segmented polyurethane, and PVC with butadiene acrylonitrile rubber are described. Studies of the temperature dependence of segmental orientation show that the orientation achievable is strongly dependent upon the viscoelastic state of the blend. The orientation of the soft and hard segments of a polyether urethane-urea was shown to depend on domain morphology as affected by hard segment weight fraction, hard and soft segment length, and hard domain urea content." @default.
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- W2492046918 date "1984-05-01" @default.
- W2492046918 modified "2023-09-27" @default.
- W2492046918 title "Segmental Orientation in Multicomponent Polymer Systems" @default.
- W2492046918 doi "https://doi.org/10.1021/ba-1984-0206.ch008" @default.
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