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- W2492114512 abstract "CONTENTS 1 6.0 Introduction 6.1 Quantum Mechanics of Vibration and Rotation 6.2 Semiclassical Methods 6.2.1 The semiclassical quantization condition 6.2.2 The Rydberg-Klein-Rees (RKR) inversion procedure 6.2.3 Near-dissociation theory (NDT) 6.2.4 Conclusions regarding semiclassical methods 6.3 Quantum-Mechanical Direct-Potential-Fit Methods 6.3.1 Overview and background 6.3.2 Potential function forms 6.3.2A Polynomial Potential Function Forms 6.3.2B The Expanded Morse Oscillator (EMO) Potential Form and the Importance of the Definition of the Expansion Variable 6.3.2C The Morse/Long-Range (MLR) Potential Form 6.3.2D The Spline-Pointwise Potential Form 6.3.3 Initial trial parameters for direct potential fits 6.4 Born-Oppenheimer Breakdown Effects 6.5 Concluding Remarks Appendix: What terms contribute to a long-range potential? Exercises References" @default.
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- W2492114512 date "2010-12-02" @default.
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- W2492114512 title "Determining Equilibrium Structures and Potential Energy Functions for Diatomic Molecules" @default.
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- W2492114512 doi "https://doi.org/10.1201/b10374-7" @default.
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